Volume 341
Main Index

Issues 1-3, Pages 1-574 (1 March 1988)

Preface Page ix Marc Atkins

Preface Page ix Kenneth R. Seddon

Introduction Pages xi-xiv M. F. Lappert

Übergangsmetall---Carbin-Komplexe : LXXXVII. (η5-C5H5)(I)2(CO)WCNEt2, der erste, carbonylhaltige Diethylaminocarbin-Komplex des Wolframs mit einer hohen Oxidationszahl Pages C35-C38 Alexander Constantin Filippou, Ernst Otto Fishcer

Author index Pages C54-C55

The conformations of six-membered indium-arsenic and gallium-antimony rings Pages C1-C5 Alan H. Cowley, Richard A. Jones, Kenneth B. Kidd, Christine M. Nunn, Donald L. Westmoreland

Subject index Pages C56-C61

Analytically significant steric effects on 29Si NMR chemical shifts as observed in trimethylsilylated steroids Pages C6-C8 Jan Schraml, Jan ermák, Václav Chvalovský, Alexander Kasal, Claus Bliefert and, Eduard Krahé

Synthesis and structure of two tris(pyrazolyl)boratotin(II) compounds Pages C27-C30 Alan H. Cowley, Rolf L. Geerts, Christine M. Nunn, Carl J. Carrano

Cis- and trans-influences in octahedral complexes of methyltin trihalides and tin tetrahalides with tertiary phosphines Pages C31-C34 O. A. Reutov, V. S. Petrosyan, N. S. Yashina, E. I. Gefel

Synthesis of AsMe2-bridged triosmium clusters: X-ray crystal structures of [Os3H(CO)11(μ-AsMe2)] and [Os3(μ-H)2(CO)8(μ-AsMe2)2] Pages C45-C49 Karlheinz Guldner, Brian F. G. Johnson, Jack Lewis, Steven M. Owen, Paul R. Raithby

Synthesis of μ-carbene complexes of cobalt from substituted diazirines Pages C50-C52 Stephen A. Benyunes, Penny A. Chaloner

IR laser photosensitized decomposition of 1-methyl-1-silacyclobutane. Efficient gas-phase polymer deposition Pages C13-C16 Josef Pola, Václav Chvalovský, Elvira A. Volnina and, Leonid E. Guselnikov

Kinetic spectroscopy of diphenylgermylene Ph2Ge following laser flash photolysis of bis(trimethylsilyl) diphenylgermane (Me3Si)2GePh2 Pages C17-C22 Stanislaw Konieczny, S. Joshua Jacobs, Janet K. Braddock Wilking, Peter Paul Gaspar

Gmelin Handbook of Inorganic Chemistry 8th edition, Mn—Manganese, Part D5: Coordination Compounds 5 : Springer Verlag, Berlin, Heidelberg, New York, Tokyo, 1987, xix + 749 pages, DM 1541. ISBN 3-540-93550-9. Page C53 Joseph Chatt

Primary aminomethylation of organometallic compounds via N,N-bis(trimethylsilyl)methylthiomethylamine Pages C23-C26 Luisa Fiocca, Mariella Fiorenza, Gianna Reginato, Alfredo Ricci, Pasquale Dembech and, Giancarlo Seconi

Synthesis and electrochemistry of di-η5-cyclopentadienyltungsten(IV) and -molybdenum(IV) crown ether complexes Pages C39-C44 Enqin Fu, Malcolm L. H. Green, Valerie J. Lowe, Seth R. Marder

Silacyclopropanes from the reaction of silenes with Wittig reagents Pages C9-C12 A. G. Brook, Andew MacMillan

Isolation and X-ray crystal structures of the organolithium etherate complexes, [Li(Et2O)2(CPh3)] and [{Li(Et2O)(2,4,6-(CHMe2)3C6H2)}2] Pages 1-9 R. A. Bartlett, H. V. R. Dias, P. P. Power

Ouverture d'oxirannes et d'oxétannes par des organolithiens fluorovinyliques en présence de BF3 · Et2O Pages 11-18 Thierry Dubuffet, Raymond Sauvêtre, Jean-F. Normant

Competition among multihapto bonding, solvation, and aggregation. The η1/η2 infinite-chain X-ray structure of indenylsodium · N,N,N′,N′-tetramethyl-1,2-diaminoethane Pages 19-38 Christian Schade, Paul von Ragué Schleyer, Peter Gregory, Hans Dietrich and, Waruno Mahdi

Organo-magnesium reagents: the crystal structures of [Mg(anthracene)(THF)3] and [Mg(triphenylmethyl)Br(OEt2)2] Pages 39-51 Lutz M. Engelhardt, Stephen Harvey, Colin L. Raston, Allan H. White

Bonding studies on zinc, cadmium, and mercury alkyls and amides, Zn(CH2EMe3)2 (E = C or Si) and M[N(SiMe3)2]2 (M = Zn, Cd, or Hg). Heats of Hydrolysis, standard heats of formation, and Zn---C and M---N (M = Zn, Cd, or Hg) bond energy terms Pages 53-62 Ismail E. Gümrükçüoglü, John Jeffery, Michael F. Lappert, J. Brian Pedley, Audesh K. Rai

An ESR study of the mercuration of the biphenylene radical cation. Evidence for a homolytic mechanism of mercuration Pages 63-71 John L. Courtneidge, Alwyn G. Davies, Deborah C. McGuchan, Safieh N. Yazdi

Chiral synthesis via organoboranes : XVI. Boroxazolidones derived from α-amino acids and borinic or boronic esters. A simple procedure for upgrading borinates and boronates to materials of high optical purity Pages 73-81 Herbert C. Brown, Ashok K. Gupta

Polymerization and copolymerization of β-butyrolactone by aluminium compounds Pages 83-93 N. C. Billingham, M. G. Proctor, J. D. Smith

Beiträge zur Chemie der Silicium-Stickstoffverbindungen : CLXIV. 1-Silaisoindolinone: Strukturanaloga des Saccharins, und verwandte Verbindungen Pages 95-108 Ulrich Wannagat, Rolf Schrader

Bildung siliciumorganischer Verbindungen , : CVII. Bildung und Struktur des trans-trans-trans- Nonamethyl-hexasilaperhydrophenalens Pages 109-117 G. Fritz, H. Volk, M. Straub

N,N-Bis(trimethylstannyl)di-t-butylfluorsilylamin; ein sterisch fixiertes Molekül Pages 119-124 Dietmar Stalke, Uwe Klingebiel, George M. Sheldrick

Catalyseurs pour la transformation de polydiméthylsilanes en polycarbosilanes Pages 125-132 Françoise Duboudin, Marc Birot, Odile Babot, Jacques Dunoguès, Raymond Calas

Chemistry of organosilicon compounds : CCXXXVI. Structure of conformationally stable 1-(p-bromophenyl)-4-t-butyl-1-methyl-1-silacyclohexane and stereochemistry of halodesilylation Pages 133-143 Hideki Sakurai, Masashi Murakami, Kiyoshi Takeuchi, Chizuko Kabuto

Donoraddukte des Silanimins Me2Si=NSitBu3: Darstellung, Stabilität, Reaktivität Pages 145-163 Nils Wiberg, Klaus Schurz

Electrophilic cleavage reations of carbon---silicon bonds in neutral hexacoordinate silicon compounds: diorgano(phthalocyaninato)silicon Pages 165-179 Kohei Tamao, Munetaka Akita, Hidehito Kato, Makoto Kumada

Formation and reactivity of trimethylsilylmethyl cyclopentenones Pages 181-185 David C. Billington, William J. Kerr, Peter L. Pauson

Generation of silanimines by photolysis of hindered azidosilanes Pages 187-198 Steven S. Zigler, Leighta M. Johnson, Robert West

New mechanisms for the base-catalyzed cleavage of Si---Si bonds in organopolysilanes: the base-catalyzed solvolysis of pentaphenyldisilanecarboxylic acid and pentaphenyldisilanol in ethanol/water media Pages 199-211 Omar W. Steward, James L. Williams

Nucleophile-assisted racemisation of halosilanes; an alternative pathway involving halide exchange Pages 213-224 Alan R. Bassindale, Juliana C. -Y. Lau, Peter G. Taylor

Nucleophilic cleavage of the Si---C bond in organotrifluorosilanes and diorganodifluorosilanes Pages 225-229 M. G. Voronkov, N. F. Chernov, E. M. Perlova

Organosilicon derivatives of cyclic and high polymeric phosphazenes Pages 231-239 Harry R. Allcock, David J. Brennan

Preparation and X-ray crystal structure of an unusual bicyclic trisilane-tris(disoloxane) Pages 241-245 Salih S. Al-Juaid, Youcef Derouiche, Peter B. Hitchcock, Paul D. Lickiss

Regio- and site-selective cycloadditions : I. The reaction of aryl azides and of ethyl diazoacetate with the bis(trimethylsilyl)polyynes, Me3Si(CC)nSiMe3 (n = 2 or 3) Pages 247-254 Richard M. Bettison, Peter B. Hitchcock, David R. M. Walton

Some examples of the contribution of gas-kinetic studies to the understanding of organosilicon reaction mechanisms Pages 255-265 Iain M. T. Davidson

Stereospecific 1,4-polymerization of 2,3-bis(trimethylsilyl)-1,3-butadiene Pages 267-271 Yi-Xiang Ding, William P. Weber

Strained-ring silicon-centred radicals: silacyclobut-1-yl and related radicals Pages 273-279 Richard A. Jackson, Antonios K. Zarkadis

Structure and dynamics of hindered organosilicon compounds. The conformation and enantiotopomerization of (chlorodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane Pages 281-291 Anthony G. Avent, Paul D. Lickiss, Alan Pidcock

Organosilicon compounds with functional groups proximate to silicon : XVII. Synthetic and mechanistic aspects of the lithiation of α,β-epoxyalkylsilanes and related α-heterosubstituted epoxides Pages 293-313 John J. Eisch, James E. Galle

73Ge NMR spectroscopic studies of organogermanium compounds Pages 315-333 E. Liepi, I. Zicmane, E. Lukevics

Hexa-t-butyldigerman und Hexa-t-butylcyclotrigerman: Moleküle mit den derzeit längsten Ge---Ge- und Ge---C-Bindungen Pages 335-343 Manfred Weidenbruch, Fred-Thomas Grimm, Marlies Herrndorf, Annemarie Schäfer, Karl Peters and, Hans Georg von Schnering

Hydrated σ-bonded organometallic cations in organic synthesis : I. Allyl-, crotyl-, 1-methylallyl-, cyclohex-2-enyl-, and cinnamyl-stannation of carbonyl compounds in water Pages 345-356 Donatella Furlani, Daniele Marton, Giuseppe Tagliavini, Michele Zordan

Isomerisations and tautomerism in phosphazene chemistry Pages 357-361 Robert A. Shaw

Transition metal complexes of the trans-spanning ditertiary phosphine, bis{3-[bis(3-trifluoromethylphenyl)- phosphinomethyl]phenyl} ether Pages 363-366 Pramesh N. Kapoor

Some dimethyl{tris(trimethylsilyl)methyl} silanolato derivatives of tantalum(V), chromium(III) and manganese(II) Pages 367-371 Helen Blanchard, Michael B. Hursthouse, Alice C. Sullivan

Iron-molybdenum and iron-tungsten sulphido clusters containing hydrazido(2−) ligands. The synthesis and X-ray crystal and molecular structure of [{Fe(CO)3(μ3-S)}2Mo(NNMe2)2(PPh3)](Fe-Fe) · CH2Cl2 Pages 373-380 Peter T. Bishop, Jonathan R. Dilworth, Stephen Morton, Jon A. Zubieta

95Mo studies of ligands relevant to dinitrogen fixation: NMR spectrochemical series based on 95Mo shielding Pages 381-389 Mark Hughes, Joan Mason, G. Jeffery Leigh and, Raymond L. Richards

Synthesis of complexes with tungsten---cobalt bonds via alkylidyne group coupling reactions; crystal structure of the compound [Wco{μ-C(C6H4Me-4)C(O)C(C6H4Me-4)}(CO)5(η-C5H5)] Pages 391-406 Ian J. Hart, Aynsley E. Jardin, John C. Jeffery, F. Gordon, A. Stone

Dialkylaminophosphorus metal carbonyls : VII. Trinuclear iron carbonyl derivatives from reactions of disodium octacarbonyldiferrate with (dialkylamino)dichlorophosphines Pages 407-414 R. B. King, G. S. Chorghade

Organometalloidal derivatives of the transition metals : XVI. Thermal decarbonylation of (η5-C5H5)Fe(CO)(PPh3)COR (R = CH3, CH2SiMe3, and CH2SiMe2Ph) Pages 415-419 Keith H. Pannell, John R. Rice

Synthesis and reactivity of (μ-σ,π-acetylide) (μ-alkane- and μ-arene-thiolate)bis(tricarbonyliron) complexes Pages 421-437 Dietmar Seyferth, Jeffrey B. Hoke, David R. Wheeler

The pentacyanonitrosylferrate(2—) ion : IV. Reactions with the carbanions of pentane-2,4-dione and 3-methylpentane-2,4-dione Pages 439-446 Anthony R. Butler, Adrianne M. Calsy, Christopher Glidewell

The synthesis and properties of [Fe3(CO)11(RCN)] derivatives, and a high-yield general route to mono- and di-substituted derivatives of [Fe3(CO)12]; the crystal and molecular structure of [Fe3(CO)11(NCC6H4-2-Me)] Pages 447-456 Christine J. Cardin, David J. Cardin, Norah B. Kelly, Gerard A. Lawless, Michael B. Power

Tri- and tetra-metallic complexes containing phospha-alkyne ligands. First examples of μ3(η2-) bonded phospha-alkynes; crystal and molecular structure of [Fe2Pt(Ph2PCH2CH2PPh2)(CO)6(Me3CCP)] Pages 457-472 Saud I. Al-Resayes, Peter B. Hitchcock, Mohamed F. Meidine, John F. Nixon

Ligand substitution in [CoxRh4−x(CO)12] (x = 3 or 2) with tertiary phosphines or phosphites, including the X-ray structure of [Co2Rh2(CO)11(PPh3)] Pages 473-483 Maria Bojczuk, Brian T. Heaton, S. Johnson, Carlo A. Ghilardi and, Annabella Orlandini

An EPR investigation of the thermodynamics and kinetics of a reversible intramolecular metal-ligand electron transfer in rhodium complexes Pages 485-494 G. A. Abakumov, G. A. Razuvaev, V. I. Nevodchikov, V. K. Cherkasov

Halocarbon chelation in [Ir(cod)(η2-o-HalC6H4PPh2)]SbF6 (Hal = Br, Cl): structural and chemical studies Pages 495-509 Mark J. Burk, Robert H. Crabtree, Elizabeth M. Holt

Kinetic studies on the oxidation of dichlorotetracarbonyldirhodium(I) by hydrogen peroxide Pages 511-522 John R. Chipperfield, May Shana's, David E. Webster

Molecular orbital analysis of some carbonyl cluster compounds with close-packed metallic arrangements Pages 523-534 D. Michael P. Mingos, Lin Zhenyang

Tetrakis(trimethylphosphine)nickel(0) Pages 535-541 Anthony G. Avent, F. Goeffrey N. Cloke, Jeremy P. Day, Elaine A. Seddon, Kenneth R. Seddon, Stephen M. Smedley

Synthesis of [Pt(CCH)2(dppm-P)2] (dppm = Ph2Pch2PPh2) and formation of heterobimetallic complexes of platinum with silver, gold, rhodium, iridium, and tungsten Pages 543-548 Stuart W. Carr, Paul G. Pringle, Bernard L. Shaw

Theoretical study of the catalytic activity of platinum(II) and palladium(II) complexes in cis-trans isomerisations of alkenes Pages 549-557 Robert Ponec, Roman eicha

The preparation and dynamic behaviour of platinum(IV) derivatives of macrocyclic thioethers Pages 559-567 Edward W. Abel, Paul D. Beer, Ian Moss, Keith G. Orrell, Vladimir ik, Paul A. Bates and, Michael B. Hursthouse

Chloride and alkoxide alkoxometallates and termetallic isopropoxides of copper(II) Pages 569-574 Raj K. Dubey, Anirudh Singh, Ram C. Mehrotra